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BASF Corporation
Material Safety Data Sheet
BASF CORPORATION
1609 BIDDLE AVENUE
WYANDOTTE, MI 48192
(734) 324-5250
EMERGENCY TELEPHONE: (800) 424-9300 CHEMTREC
(800) 832-HELP (BASF Hotline)
BOTH NUMBERS ARE AVAILABLE DAYS, NIGHTS, WEEKENDS, & HOLIDAYS.
ULTRAFORM(R) H 4320
UNCOLORED, ACETAL COPOLYMER
Product ID: NPP
530772
Common Chemical
Name: Polyoxymethylene Copolymer;
POM
Synonyms: ULTRAFORM
Molecular Formula: POLYMER
Chemical Family: Acetal Copolymer
Molecular Wt.: NOT
APPLICABLE
Chemical Name: CAS Amount
POM 25214-85-1 > 99.0 %
PEL/TLV NOT
ESTABLISHED
*Formaldehyde is not a component but may be released during processing or if exposed to extreme heat.
Color: Opaque
Form/Appearance: Pellets
Odor: Odorless
Odor Intensity: Not available
Typical Low/High U.O.M.
Specific Gravity: 1.35 - 1.45
Bulk Density: 850 KG/CU.M
pH: NOT AVAILABLE
Typical Low/High Deg. @ Pressure
Boiling Pt: NOT
AVAILABLE
Freezing Pt: NOT
AVAILABLE
Decomp. Tmp: > 240 C 1 ATMOSPHERES
Solubility in
Water Description: Insoluble
Typical Low/High Deg. Method
Flash Point: 320 -
340 C ASTMD 1929
Autoignition: NOT
AVAILABLE
Extinguishing
Media: Use water fog, foam
or dry chemical extinguishing media.
Fire Fighting
Procedures: Firefighters should
be equipped with self-contained breathing apparatus and turn out gear.
Unusual Hazards: Formaldehyde
may be released if product is exposed to excessive heat or fire. Airborne dust
may be explosive. Explosibility of dusts increases with decreasing particle
size, so the production of fines should be minimized.
Routes of entry for
solids and liquids include eye and skin contact, ingestion and inhalation.
Routes of entry for gases include inhalation and eye contact. Skin contact may
be a route of entry for liquefied gases.
Acute Overexposure
Effects:
Contact of the
decomposition products with the eyes and skin may result in irritation.
ULTRAFORM itself is harmless. Molten materials can cause thermal burns. If
ULTRAFORM is subjected to excessive heat the primary decomposition is
formaldehyde.
Formaldehyde
is highly irritating to the upper respiratory tract and eyes. Repeated exposure
may lead to sensitization in some individuals. Formaldehyde overexposure can
cause symptoms of bronchial asthma, either by direct irritation or
sensitization. Inhalation may cause irritation to the respiratory tract,
breathing difficulties, coughing, CNS effects, pneumonitis and pulmonary edema.
Chronic
Overexposure Effects:
Chronic
inhalation studies in animals have shown that formaldehyde causes nasal cancer
in rats. The International Agency for Research
on Cancer
(IARC) has classified formaldehyde as a carcinogen in Group 2A, and the
National Toxicology Program (NTP) included formaldehyde in its Annual Report on
Carcinogens. OSHA regulates formaldehyde in 29 CFR 1910.1048.
The OSHA TWA
for formaldehyde is 0.75 ppm. The ACGIH TLV is I ppm. The OSHA and ACGIH STEL
is 2 ppm.
First Aid
Procedures - Skin:
Wash affected
areas with soap and water. Remove and launder contaminated clothing before reuse.
If irritation develops, get medical attention.
First Aid
Procedures - Eyes:
If contacted
with decomposition products immediately wash eyes with running water for 15
minutes. If irritation develops, get medical attention.
First Aid
Procedures - Ingestion:
Ingestion not
likely in pellet form. If ingested, seek medical attention.
First Aid
Procedures - Inhalation:
Move to fresh
air. Aid in breathing, if necessary, and get immediate medical attention.
First Aid
Procedures - Notes to Physicians:
None known.
First Aid
Procedures - Aggravated Medical Conditions:
No data is
available which addresses medical conditions that are generally recognized as
being aggravated by exposure to this product. Please refer to the Toxicological
Information section for effects observed in animals.
First Aid
Procedures - Special Precautions:
None
Stability Data:
Stable
Incompatability:
Avoid contact
with polyvinylchloride (PVC) and other plastic that contain halogenated flame
retardants when processing ULTRAFORM. Avoid contact with strong oxidizers and
inorganic acids, e.g. hydrochloric, sulfuric acid etc.
Conditions/Hazards
to Avoid:
Avoid extreme
heat; decomposition occurs at temperatures above 240C
Hazardous
Decomposition/Polymerization:
Hazardous Decomposition
Products: Formaldehyde and CO.
Corrosive
Properties:
Not
corrosive.
Oxidizer
Properties:
Not an
oxidizer
Clothing:
Gloves,
coveralls, apron, and boots as necessary to prevent contact.
Eyes:
Safety
glasses with side-shields should be worn during industrial operations.
Respiration:
NIOSH/MSHA
approved organic vapor cartridge respirator may be needed when handling molten
material.
Ventilation:
Local exhaust
ventilation at source may be needed when processing molten material.
Explosion
Proofing:
None
required.
General:
Reclaim for
processing if possible. Spills should be contained and placed in suitable
containers for disposal in a licensed facility. This material is not regulated
by RCRA or CERCLA ("Superfund").
Waste Disposal:
Incinerate or
bury in a licensed facility. Do not discharge into waterways or sewer systems
without proper authority.
Container Disposal:
Unused
material and empty containers must be disposed of in accordance with local,
state and federal regulations.
General:
Avoid extreme
heat.
Protect from
moisture during transportation and storage.
Pellet-handling
equipment should be grounded to prevent buildup of electrostatic charge.
Pellets on
floor may be slippery and cause falls.
Avoid dust
accumulation.
Keep
containers closed.
TSCA Inventory Status Listed on Inventory: YES
RCRA Haz. Waste No
.: N/A
CERCLA: NO
Reportable Qty.: (If YES)
This product is not
hazardous according to the OSHA Hazard Communication Standard.
Ultraform is not formulated with a chemical subject
to Calif. Prop. 65. Improper processing, i.e. excessive heating, presence of
acidic materials/oxidizing agents can cause decomposition generating formaldehyde
(FA), "known to the State of California to cause cancer". No adverse
health effects or exposure to FA is anticipated during normal handling while
solid or when handling finished articles under ambient temperature conditions. Prop.
65 labeling requirement becomes an issue if expected use results in FA release,
making it the manufacturer's responsibility to warn
employees/customers/downstream users of potential FA exposure.
SECTION 11 - TRANSPORTATION INFORMATION
DOT Proper Shipping Name: NONE
DOT Technical Name:
DOT Primary Hazard Class: NONE
DOT Secondary Hazard Class: NONE
DOT Label Required: NONE
DOT Placard
Required: NONE
DOT Poison Constituent: NONE
BASF Commodity
Codes: 812 UN/NA Code: N/A E/R Guide: N/A
Bill of Lading
Description: PLASTIC
PELLETS OR POWDER, O/T EXPANDED.
CLASS: P. G. SHIPPING
NAME:
IATA: NONE N/A NONE
IMO: NONE N/A NONE
TDG: NONE N/A NONE
"IMPORTANT:
WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE
PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR
GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE,
WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR
YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER
EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR
INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY
BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO
CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE
CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY
UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION
FURNISHED BY BASF HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR
LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS
OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK". BASF
CORPORATION WILL NOT MAKE ITS PRODUCTS AVAILABLE TO CUSTOMERS FOR USE IN THE
MANUFACTURE OF MEDICAL DEVICES WHICH ARE INTENDED FOR PERMANENT IMPLANTATION IN
THE HUMAN BODY OR IN PERMANENT CONTACT WITH INTERNAL BODILY TISSUES OR FLUIDS.
WE AT BASF TAKE PRIDE IN OUR PRODUCTS, AND OUR TRADITION OF DEVELOPING
INNOVATIVE APPLICATIONS IN PARTNERSHIP WITH OUR CUSTOMERS. HOWEVER, THE POSSIBILITY
OF BEING REQUIRED TO RESPOND TO UNFOUNDED LITIGATION AND/OR CLAIMS ARISING OUT
OF CONCERNS RELATING TO SUCH USE PRESENTS AN UNACCEPTABLE RISK TO THE COMPANY.