BASF Corporation

Material Safety Data Sheet

 

BASF CORPORATION

1609 BIDDLE AVENUE

WYANDOTTE, MI 48192

(734) 324-5250

EMERGENCY TELEPHONE:   (800) 424-9300 CHEMTREC

(800) 832-HELP (BASF Hotline)

BOTH NUMBERS ARE AVAILABLE DAYS, NIGHTS, WEEKENDS, & HOLIDAYS.

 

SECTION I - PRODUCT INFORMATION

 

ULTRAFORM(R) H 4320 UNCOLORED, ACETAL COPOLYMER

Product ID:                              NPP 530772

Common Chemical Name:        Polyoxymethylene Copolymer; POM

Synonyms:                                ULTRAFORM

Molecular Formula:                   POLYMER

Chemical Family:                      Acetal Copolymer

Molecular Wt.:                         NOT APPLICABLE

 

SECTION 2 – INGREDIENTS

 

Chemical Name:                                                                       CAS                            Amount

POM                                                                                  25214-85-1                      > 99.0 %

PEL/TLV NOT ESTABLISHED

*Formaldehyde is not a component but may be released during processing or if exposed to extreme heat.

 

SECTION 3 - PHYSICAL PROPERTIES

 

Color:                                       Opaque

Form/Appearance:                    Pellets

Odor:                                       Odorless

Odor Intensity:                          Not available

Typical                         Low/High                     U.O.M.

Specific Gravity:                                                                       1.35 - 1.45

Bulk Density:                                          850                                                                KG/CU.M

pH:                                           NOT AVAILABLE

Typical                         Low/High         Deg.     @        Pressure

Boiling Pt:                                 NOT AVAILABLE

Freezing Pt:                              NOT AVAILABLE

Decomp. Tmp:                                     >  240                                                   C        1          ATMOSPHERES

Solubility in Water Description: Insoluble

 

SECTION 4 - FIRE AND EXPLOSION DATA

 

Typical                         Low/High         Deg.                 Method

Flash Point:                                                                               320 - 340          C               ASTMD 1929

Autoignition:                             NOT AVAILABLE

Extinguishing Media:                 Use water fog, foam or dry chemical extinguishing media.

Fire Fighting Procedures:          Firefighters should be equipped with self-contained breathing apparatus and turn out gear.

Unusual Hazards:                      Formaldehyde may be released if product is exposed to excessive heat or fire. Airborne dust may be explosive. Explosibility of dusts increases with decreasing particle size, so the production of fines should be minimized.

 
SECTION 5 - HEALTH EFFECTS

 

Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases.

 

Acute Overexposure Effects:

Contact of the decomposition products with the eyes and skin may result in irritation. ULTRAFORM itself is harmless. Molten materials can cause thermal burns. If ULTRAFORM is subjected to excessive heat the primary decomposition is formaldehyde.

Formaldehyde is highly irritating to the upper respiratory tract and eyes. Repeated exposure may lead to sensitization in some individuals. Formaldehyde overexposure can cause symptoms of bronchial asthma, either by direct irritation or sensitization. Inhalation may cause irritation to the respiratory tract, breathing difficulties, coughing, CNS effects, pneumonitis and pulmonary edema.

Chronic Overexposure Effects:

Chronic inhalation studies in animals have shown that formaldehyde causes nasal cancer in rats. The International Agency for Research

on Cancer (IARC) has classified formaldehyde as a carcinogen in Group 2A, and the National Toxicology Program (NTP) included formaldehyde in its Annual Report on Carcinogens. OSHA regulates formaldehyde in 29 CFR 1910.1048.

The OSHA TWA for formaldehyde is 0.75 ppm. The ACGIH TLV is I ppm. The OSHA and ACGIH STEL is 2 ppm.

First Aid Procedures - Skin:

Wash affected areas with soap and water. Remove and launder contaminated clothing before reuse. If irritation develops, get medical attention.

First Aid Procedures - Eyes:

If contacted with decomposition products immediately wash eyes with running water for 15 minutes. If irritation develops, get medical attention.

First Aid Procedures - Ingestion:

Ingestion not likely in pellet form. If ingested, seek medical attention.

First Aid Procedures - Inhalation:

Move to fresh air. Aid in breathing, if necessary, and get immediate medical attention.

First Aid Procedures - Notes to Physicians:

None known.

First Aid Procedures - Aggravated Medical Conditions:

No data is available which addresses medical conditions that are generally recognized as being aggravated by exposure to this product. Please refer to the Toxicological Information section for effects observed in animals.

First Aid Procedures - Special Precautions:

None

 

SECTION 6 - REACTIVITY DATA

 

Stability Data:

Stable

Incompatability:

Avoid contact with polyvinylchloride (PVC) and other plastic that contain halogenated flame retardants when processing ULTRAFORM. Avoid contact with strong oxidizers and inorganic acids, e.g. hydrochloric, sulfuric acid etc.

Conditions/Hazards to Avoid:

Avoid extreme heat; decomposition occurs at temperatures above 240C

Hazardous Decomposition/Polymerization:

Hazardous Decomposition Products: Formaldehyde and CO.

Corrosive Properties:

Not corrosive.

Oxidizer Properties:

Not an oxidizer

 

SECTION 7 - PERSONAL PROTECTION

 

Clothing:

Gloves, coveralls, apron, and boots as necessary to prevent contact.

Eyes:

Safety glasses with side-shields should be worn during industrial operations.

Respiration:

NIOSH/MSHA approved organic vapor cartridge respirator may be needed when handling molten material.

Ventilation:

Local exhaust ventilation at source may be needed when processing molten material.

Explosion Proofing:

None required.

 
SECTION 8 - SPILL-LEAK/ENVIRONMENTAL

 

General:

Reclaim for processing if possible. Spills should be contained and placed in suitable containers for disposal in a licensed facility. This material is not regulated by RCRA or CERCLA ("Superfund").

Waste Disposal:

Incinerate or bury in a licensed facility. Do not discharge into waterways or sewer systems without proper authority.

Container Disposal:

Unused material and empty containers must be disposed of in accordance with local, state and federal regulations.

 

SECTION 9 - STORAGE AND HANDLING

 

General:

Avoid extreme heat.

Protect from moisture during transportation and storage.

Pellet-handling equipment should be grounded to prevent buildup of electrostatic charge.

Pellets on floor may be slippery and cause falls.

Avoid dust accumulation.

Keep containers closed.

 

SECTION 10 - REGULATORY INFORMATION

 

TSCA Inventory Status Listed on Inventory:                              YES

 

RCRA Haz. Waste No .:    N/A

CERCLA:   NO     Reportable Qty.: (If YES)

This product is not hazardous according to the OSHA Hazard Communication Standard.

Ultraform is not formulated with a chemical subject to Calif. Prop. 65. Improper processing, i.e. excessive heating, presence of acidic materials/oxidizing agents can cause decomposition generating formaldehyde (FA), "known to the State of California to cause cancer". No adverse health effects or exposure to FA is anticipated during normal handling while solid or when handling finished articles under ambient temperature conditions. Prop. 65 labeling requirement becomes an issue if expected use results in FA release, making it the manufacturer's responsibility to warn employees/customers/downstream users of potential FA exposure.

 

SECTION 11 - TRANSPORTATION INFORMATION

 

DOT Proper Shipping Name:                NONE

DOT Technical Name:

DOT Primary Hazard Class:                 NONE

DOT Secondary Hazard Class:             NONE

DOT Label Required:                           NONE

DOT Placard Required:                        NONE

DOT Poison Constituent:                      NONE

BASF Commodity Codes:                    812                  UN/NA Code: N/A                  E/R Guide: N/A

Bill of Lading Description:                     PLASTIC PELLETS OR POWDER, O/T EXPANDED.

CLASS:                       P. G.                            SHIPPING NAME:

IATA:              NONE                         N/A                                         NONE

 

IMO:                NONE                         N/A                                         NONE

 

TDG:                NONE                         N/A                                         NONE

 

"IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK". BASF CORPORATION WILL NOT MAKE ITS PRODUCTS AVAILABLE TO CUSTOMERS FOR USE IN THE MANUFACTURE OF MEDICAL DEVICES WHICH ARE INTENDED FOR PERMANENT IMPLANTATION IN THE HUMAN BODY OR IN PERMANENT CONTACT WITH INTERNAL BODILY TISSUES OR FLUIDS. WE AT BASF TAKE PRIDE IN OUR PRODUCTS, AND OUR TRADITION OF DEVELOPING INNOVATIVE APPLICATIONS IN PARTNERSHIP WITH OUR CUSTOMERS. HOWEVER, THE POSSIBILITY OF BEING REQUIRED TO RESPOND TO UNFOUNDED LITIGATION AND/OR CLAIMS ARISING OUT OF CONCERNS RELATING TO SUCH USE PRESENTS AN UNACCEPTABLE RISK TO THE COMPANY.